Alvaro Morata scored twice for Spain, while Fabio Quagliarella entered the record books for Italy in Tuesday's European Qualifiers.
The final round of Nations League group games take place on Sky Sports on Tuesday, with promotion and relegation still to be decided.
Bulgaria, Greece, Romania and Serbia are coming together to make a joint bid to host the 2030 World Cup.
Dusan Tadic produced a contender for one of the worst penalty misses of the season as Serbia drew 0-0 with Romania.
Scotland, Italy and Portugal are all in UEFA Nations League action on Saturday, and you can watch every game live on Sky Sports.
Portugal and Scotland are in action as the UEFA Nations League returns on Thursday, while Wales, Spain and France play friendlies.
Portugal, without talisman Cristiano Ronaldo, beat Italy 1-0 in the UEFA Nations League on Monday, while Turkey stunned Sweden.
Jorginho's late penalty ensured Italy's Nations League campaign got off to an unbeaten start in a 1-1 draw with Poland.
Russia extended their winless streak to seven matches with a 1-1 home draw against Turkey on Tuesday in their last warm-up game before the World Cup.
Romelu Lukaku scored twice as Belgium romped to a 4-0 victory over Saudi Arabia on Tuesday night.
Nottingham Forest have made a double loan swoop for goalkeeper Costel Pantilimon and winger Ashkan Dejagah.
Group C winners Germany closed their qualifying campaign with a 100 per cent record following a 5-1 win against Azerbaijan in Kaiserslautern.
The penultimate round of World Cup Qualifiers kicks off live on Sky Sports on Thursday, with Scotland and Northern Ireland in action.
Germany thrashed Norway 6-0 and there were important wins for Poland, Montenegro and Denmark in Monday's World Cup Qualifiers.
Germany needed a late goal to beat Czech Republic, while there were wins for Slovakia, Denmark and Norway on Friday night.
Germany hit seven past San Marino on Saturday evening and there were also wins for Poland, Slovakia and Denmark.
Germany will look to continue their perfect start in the World Cup Qualifiers when they travel to Azerbaijan on Sunday, live on Sky Sports.
Former Steaua Bucharest and Atletico Madrid defender Daniel Prodan has died at the age of 44.
Italy and Germany fought out a goalless draw, while France also drew a blank with Ivory Coast in friendlies on Tuesday night.
Watch the dramatic moment Robert Lewandowski fell to the floor after a flare exploded near him in Poland's clash in Romania.
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